35926-81-9

Basic information

• Product Name: {2-ethoxy-1-[hydroxy(5-hydroxy-2-phenyl-1,3-dioxan-4-yl)methyl]-2-oxoethylidene}diazenium (non-preferred name)
• CAS NO: 35926-81-9
• Molecular Formula: C₁₅H₁₈N₂O₆
• Molecular Weight: 323.3206
• Mol File: 35926-81-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {2-ethoxy-1-[hydroxy(5-hydroxy-2-phenyl-1,3-dioxan-4-yl)methyl]-2-oxoethylidene}diazenium (non-preferred name)(CAS DataBase Reference)
• NIST Chemistry Reference: {2-ethoxy-1-[hydroxy(5-hydroxy-2-phenyl-1,3-dioxan-4-yl)methyl]-2-oxoethylidene}diazenium (non-preferred name)(35926-81-9)
• EPA Substance Registry System: {2-ethoxy-1-[hydroxy(5-hydroxy-2-phenyl-1,3-dioxan-4-yl)methyl]-2-oxoethylidene}diazenium (non-preferred name)(35926-81-9)

Safety Data

• Hazardous Substances Data: 35926-81-9(Hazardous Substances Data)

Usage

General Description

{2-ethoxy-1-[hydroxy(5-hydroxy-2-phenyl-1,3-dioxan-4-yl)methyl]-2-oxoethylidene}diazenium is a chemical compound with a complicated molecular structure. It is a diazeniumdiolate, which refers to a class of organic compounds containing the functional group N2O2, formed by the reaction of nitric oxide and a nucleophile. The compound contains a hydroxy group and an ethoxy group, as well as a phenyl ring and a dioxane ring. The presence of multiple functional groups suggests that this compound may have potential applications in medicinal chemistry or materials science, although its non-preferred name indicates that it may not be widely recognized or used in the scientific community.

Relevant articles and documents

Diazo Derivatives of Sugars. Synthesis of methyl 2-deoxy-2-Diazo-d-arabino-Hexonate, Its Behaviour on Photolysis and Thermolysis, and Conversion into a Pyrazole Derivative

The action of nitrous acid on methyl 2-amino-2-deoxy-d-gluconate hydrochloride (5) and acetylation of the product gives methyl 3,4,5,6-tetra-O-acetyl-2deoxy-2-diazo-d-arabino-hexonate (6); 4,6-O-benzylidene analogs of the methyl (4) and ethyl (3) esters are similarly prepared. Photolysis of the diazo sugar 6 in isopropyl alcohol gives mainly methyl 3,4,5,6-tetra-O-acetyl-2-deoxy-d-arabino-hexonate (13) and a small proportion of methyl 4,5,6-tri-O-acetyl-2,3-dideoxy-trans,-d-erythro-hex2-enoate (14), whereas photolysis of 6 in methanol gave a cis,trans mixture of methyl 3,4,5,6-tetra-O-acetyl-2-deoxy-d-erythro-hex-2-enoate (10); the same mixture (10) of enol acetates was obtained by thermolysis of 6. The diazo sugar 6 underwent cycloaddition with phenylacetylene to give a crystalline (R or S)-3-(d-arabino-tetraacetoxybutyl)-3-methoxycarbonyl-5-phenyl-3H-pyrazole (9) in 85% yield.