35935-24-1Relevant academic research and scientific papers
(3-sulfinylpropyl)tins and (3-sulfonylpropyl)tins: Studies on intramolecular coordination
Swami, Kamal,Nebout, Brigitte,Farah, Dan,Krishnamurti, Ramesh,Kuivila, Henry G.
, p. 2370 - 2376 (2008/10/08)
A series of sulfoxides of the structures MenX3-nSn(CH2)3SOC2H 5 and MenX3-nSn(CH2)3SOC6H 5 (X = Cl or Br; n = 1-3) and sulfones MenX3-nSn(CH2)3SO2C 2H5 (X = Cl or Br; n = 1-3) have been prepared and characterized. 1H, 13C, and 119Sn NMR and IR studies were carried out. These showed that the sulfoxides with n = 1 or 2 are cyclic species with S-O → Sn coordination. The sulfones in chloroform showed evidence of intramolecularly coordinated species in equilibrium with acyclic species. Only the acyclic species were present in acetonitrile which presumably coordinates more strongly to the tin than does the sulfonyl group.
Method for controlling insects with tetrasubstituted organotin compounds
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, (2008/06/13)
Tetrasubstituted organotin compounds, which are useful for controlling insects and other pests, are disclosed. Many of these organotin compounds are new compounds.
Functionally substituted organotin compounds I. Addition of thiols to alkenyltin compounds
Ayrey,Brasington,Poller
, p. 105 - 109 (2008/10/08)
3-(Trialkylstannyl)propyl aryl sulphides (R3SnCH2CH2CH2SR′; R = Me, Et, Bu; R′ = Ph, p-tolyl) were prepared by the addition of arenethiols to allyltrialkyltin compounds. Preferential cleavage of the allyl group
