359414-52-1Relevant academic research and scientific papers
On the NH effect in ruthenium-catalysed hydrogenation of ketones: Rational design of phosphine-amino-alcohol ligands for asymmetric hydrogenation of ketones
Phillips, Scott D.,Fuentes, Jose A.,Clarke, Matthew L.
scheme or table, p. 8002 - 8005 (2010/09/14)
Chemical equation presented Redesign and reduce: The graphic shows some Ru complexes of tridentate ligands that do not contain NH substituents but can catalyse ketone reduction with zero-order dependence on ketone. In tridentate systems, a secondary amine, not a primary amine, promotes hydrogen activation. Leading on from these observations, the Ru complex of a phosphine-amino-alcohol shown above has been found to be a good hydrogenation catalyst.
Enantioselective hydrogenation and transfer hydrogenation of bulky ketones catalysed by a ruthenium complex of a chiral tridentate ligand
Diaz-Valenzuela, M. Belen,Phillips, Scott D.,France, Marcia B.,Gunn, Mary E.,Clarke, Matthew L.
, p. 1227 - 1232 (2009/08/10)
A study on the enantioselective hydrogenation of tertiary alkyl ketones catalysed by a novel class of tridentate-Ru complex is reported. In contrast to the extensively studied [RuCl2(diphos)(di-primary amine)] complexes, this new class of hydro
