359436-46-7

Basic information

• Product Name: (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-trifluoromethanesulfonyloxy-cyclopent-2-enyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester
• Synonyms: (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-trifluoromethanesulfonyloxy-cyclopent-2-enyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester
• CAS NO: 359436-46-7
• Molecular Weight: 531.55
• Mol File: 359436-46-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-trifluoromethanesulfonyloxy-cyclopent-2-enyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-trifluoromethanesulfonyloxy-cyclopent-2-enyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester(359436-46-7)
• EPA Substance Registry System: (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-trifluoromethanesulfonyloxy-cyclopent-2-enyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester(359436-46-7)

Safety Data

• Hazardous Substances Data: 359436-46-7(Hazardous Substances Data)

Upstream product

• 145100-50-1 1,1,1-trifluoro-N-(pyridin-2-yl)-N-((trifluoromethyl)sulfonyl)methane sulfonamide 
• 359436-41-2 (3aS,3bR,6S,6aS,7aR)-2,2-Dimethyl-6-(2-oxo-cyclopentyl)-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester 
• 501-53-1 benzyl chloroformate 
• 359436-33-2 [(3aS,4R,6S,6aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl]-(2-cyclopentylidene-ethyl)-carbamic acid benzyl ester 
• 359436-38-7 C₂₈H₃₅NO₄ 
• 359436-35-4 Dithiocarbonic acid O-{(3aR,4S,6R,6aS)-6-[benzyloxycarbonyl-(2-cyclopentylidene-ethyl)-amino]-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl} ester S-methyl ester 
• 359436-34-3 (2-Cyclopentylidene-ethyl)-((3aS,4R,6S,6aR)-6-hydroxy-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl)-carbamic acid benzyl ester 
• 359436-40-1 (3aS,3bR,6S,6aS,7aR)-6-(2-Hydroxy-cyclopentyl)-2,2-dimethyl-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester 
• 359436-39-8 (3aS,3bR,6S,6aS,7aR)-6-Cyclopent-1-enyl-2,2-dimethyl-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester 
• 359436-37-6 C₂₁H₂₅NO₄ 
• 302906-14-5 [(3aS,4R,6S,6aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-tetrahydro-cyclopenta[1,3]dioxol-4-yl]-carbamic acid benzyl ester 
• 133693-88-6 (2-chloroethylidene)cyclopentane 

Downstream Products

• 359436-48-9 (3S,3aS,5R,6S,6aR)-5,6-Dihydroxy-3-(2-methoxycarbonyl-pyridin-3-yl)-hexahydro-cyclopenta[b]pyrrole-1-carboxylic acid benzyl ester 
• 359436-47-8 (3aS,3bR,6R,6aS,7aR)-6-(2-Methoxycarbonyl-cyclopent-2-enyl)-2,2-dimethyl-hexahydro-1,3-dioxa-4-aza-cyclopenta[a]pentalene-4-carboxylic acid benzyl ester 

Relevant articles and documents

Stereocontrolled approach to acromelic acids

A potential stereocontrolled route to acromelic acids, neuroexitatory amino acids isolated from the mushroom Clitocybe acromelalga, has been developed by employing either concurrent Chugaev-ene reaction or retro-Diels-Alder-ene reaction and regioselective pyridinecarboxylate formation reaction as the key steps.