359448-31-0Relevant articles and documents
Diastereoselective synthesis of diamino 1,2-diols from homochiral α-aminoacylsilanes
Bonini,Comes-Franchini,Fochi,Lunazzi,Mazzanti,Mazzanti,Ricci,Varchi
, p. 995 - 998 (2001)
We have developed a new synthetic access to stereodefined diamino 1,2-diols starting from homochiral α-aminoacylsilanes. A [3+2] cycloaddition with benzo nitrile oxide of the vinylated adducts and a reductive ring opening constitute key steps of the reaction sequence.