35948-16-4

Basic information

• Product Name: Acetamide, 2-(diphenylphosphino)-
• CAS NO: 35948-16-4
• Molecular Formula: C14H14NOP
• Molecular Weight: 243.245
• Mol File: 35948-16-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetamide, 2-(diphenylphosphino)-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, 2-(diphenylphosphino)-(35948-16-4)
• EPA Substance Registry System: Acetamide, 2-(diphenylphosphino)-(35948-16-4)

Safety Data

• Hazardous Substances Data: 35948-16-4(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 125144-97-0 Diphenylphosphanyl-acetic acid phenyl ester 
• 620-73-5 phenyl chloroacetate 

Relevant articles and documents

SYNTHESIS OF SOME FUNCTIONALIZED PHOSPHINOCARBOXYLIC ACIDS

Various functionalized phosphinocarboxylic acids have been prepared by a number of complementary methods.Reactions of relatively electron-poor secondary phosphides with electron-rich halocarboxylates in liquid ammonia give high yields of phosphinocarboxylates.The substitution reactionmay proceed by a classical SN2 mechanism or by an SN rad mechanism.Reduction of the carboxilate can be a deleterious side reaction in the preparation of phosphinoacetic acids.Several phosphinopropionic acids are prepared by the Michael adition of diphenylphosphine to unsaturated esters.A valuable method proved to be the reaction of dichlorophosphinoacetic ester with functionalized organometallic reagents. Key words: Phosphine; carboxylic acid; ligand; functionalized; synthesis; NMR data.