359764-42-4Relevant academic research and scientific papers
Synthesis and insertion reactions of the cyclometalated palladium-alkyl complexes Pd(CH2CME2-o-C6H4)L2. Observation of a pentacoordinated intermediate in the insertion of SO2
Campora,Lopez,Palma,Del Rio,Carmona,Valerga,Graiff,Tiripicchio
, p. 4116 - 4126 (2001)
Palladacycles of the type Pd(CH2CMe2-o-C6H4)L2, 2, have been synthesized by treatment of the corresponding chloroalkylcomplexes Pd(CH2CMe2C6H5)ClL2 (L2 = (PMe3)2, 2a, or 1,5-cyclooctadiene (cod), 2b) with suitable bases, or by simple ligand exchange reactions from the cyclooctadiene derivative 2b. The metallacycles 2 react with activated alkynes and with sulfur dioxide, giving rise to different insertion products.
