35977-99-2Relevant academic research and scientific papers
Reaction of Li2NiBr4/THF with oxiranes: unexpected behavior of glycidic esters
Khamliche, Layachi,Robert, Albert,Bakkas, Salem
, p. 1031 - 1034 (2007/10/02)
The complex Li2NiBr4/THF usually gives bromohydrins from epoxides but reacts with α-ester epoxides or α-keto epoxides to generate a carbene species which was trapped with maleimide. - Keywords: epoxides / carbenes / dilithium tetrabromonickelate
