359827-95-5

Basic information

• Product Name: C₁₆H₁₆Br₂N₂O₆S
• Synonyms: C₁₆H₁₆Br₂N₂O₆S
• CAS NO: 359827-95-5
• Molecular Weight: 524.187
• Mol File: 359827-95-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₆H₁₆Br₂N₂O₆S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₆H₁₆Br₂N₂O₆S(359827-95-5)
• EPA Substance Registry System: C₁₆H₁₆Br₂N₂O₆S(359827-95-5)

Safety Data

• Hazardous Substances Data: 359827-95-5(Hazardous Substances Data)

Upstream product

• 121-51-7 3-nitrobenzenesulphonyl chloride 
• 17302-61-3 2-isopropyl-5-methyl-[1,4]benzoquinone-4-oxime 
• 359827-55-7 C₁₆H₁₆N₂O₆S 

Relevant articles and documents

Halogenation of some alkyl-substituted 4-aroyloxyimino-and 4-arylsulfonyloxyimino-2,5-cyclohexadienones

The chlorination and bromination of 2,3-dimethyl-, 3-methyl-6-isopropyl-, and 2,6-diisopropyl-4-aroyl(or arylsulfonyl)oxyimino-2,5-cyclohexadienones follow the proposed rules of halogenation of 4-aroyl-(or arylsulfonyl)oxyimino-2,5-cyclohexadienones: the reaction occurs preferentially at the cis-C=C bond of the quinoid ring; simultaneous halogenation at both double bonds is not observed; halogen adds mainly across unsubstituted C=C bond; no halogenation occurs at the double bond already substituted by a halogen; bromination of the C=C bond with an alkyl substituent is more difficult than chlorination; the second halogen molecule adds only after regioselective dehydrohalogenation.