359868-22-7

Upstream product

• 171231-74-6 (1S,2R,3R,4R,5S,6R)-3-Benzyloxy-2,4-dimethyl-8-oxa-bicyclo[3.2.1]octan-6-ol 
• 96691-92-8 (1R,2R,3r,4S,5S)-3-(benzyloxy)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-ene 
• 171231-75-7 endo-3-benzyloxy-endo,endo-2,4-dimethyl-6,9-dioxabicyclo[3.2.1]non-7-one 

Downstream Products

• 72485-37-1 (4R,6S,7S)-7-acetoxy-4,6-dimethyl-3-nonanone 
• 1360170-32-6 (3S,4S,6R)-3-hydroxy-7-(methoxymethoxy)-4,6-dimethylheptyl 4-methylbenzenesulfonate 
• 72522-40-8 (4R,6S,7S)-7-hydroxy-4,6-dimethyl-3-nonanone 
• 1360170-70-2 C₁₈H₃₀O₂ 
• 1360170-20-2 (S)-4-((2R,3S,4S)-3-(benzyloxy)-5-(methoxymethoxy)-4-methylpentan-2-yl)-2,2-dimethyl-1,3-dioxane 
• 1360170-67-7 (3R,5S,6S)-6-(benzyloxy)-3,5-dimethyloctan-2-one 
• 1360170-65-5 (4R,6S,7S)-7-(benzyloxy)-4,6-dimethylnonan-3-one 
• 1360170-07-5 (2R,4S,5S)-5-(benzyloxy)-2,4-dimethylheptan-1-ol 
• 1360170-36-0 (((3S,4S,6R)-7-(methoxymethoxy)-4,6-dimethylheptan-3-yloxy)methyl)benzene 
• 359868-25-0 (3R,4R,5S,6S)-5-Benzyloxy-1,7-bis-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-heptan-3-ol 
• 359868-28-3 (3S,4S,5S,6S)-4-Benzyloxy-6-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-3,5-dimethyl-tetrahydro-pyran-2-one 
• 359868-26-1 (3R,4R,5S,6S)-5-Benzyloxy-4,6-dimethyl-heptane-1,3,7-triol 
• 359868-27-2 ((2S,3S,4S,5S)-4-Benzyloxy-3,5-dimethyl-6-oxo-tetrahydro-pyran-2-yl)-acetaldehyde 
• 359868-23-8 (3S,4R,5S,6S)-5-Benzyloxy-1,7-bis-(tert-butyl-diphenyl-silanyloxy)-4,6-dimethyl-heptan-3-ol 

Relevant academic research and scientific papers

A formal stereoselective synthesis of (-)-maurenone

An efficient formal synthesis of marine polypropionate (-)-maurenone is described. Highlights of the strategy include the utilization of a desymmetrization technique and the activation of the epoxide oxygen with a silyl triflate followed by intramolecular hydride transfer - a novel transformation. Georg Thieme Verlag Stuttgart.

Synthesis of (4R,6S,7R)-7-hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5-dimethyl-2-octanone

The synthesis of (4R,6S,7R)-7-hydroxy-4,6-dimethyl-3-nonanone and (3R,5S,6R)-6-hydroxy-3,5-dimethyl-2-octanone is described as their acetates using a desymmetrization strategy as well as an Evans syn aldol strategy.

Towards the synthesis of (+)-discodermolide

An approach to the asymmetric synthesis of fragments corresponding to C1-C7 and C15-C24 of (+)-discodermolide is reported. Key elements of the successful strategy include elaboration of two advanced fragments from a common precursor.