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359902-06-0

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359902-06-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 359902-06-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,9,9,0 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 359902-06:
(8*3)+(7*5)+(6*9)+(5*9)+(4*0)+(3*2)+(2*0)+(1*6)=170
170 % 10 = 0
So 359902-06-0 is a valid CAS Registry Number.

359902-06-0Downstream Products

359902-06-0Relevant articles and documents

Unusual regio- and stereo-selectivity in Diels-Alder reactions between bulky N-phenylmaleimides and anthracene derivatives

Chen, Hao,Yao, Erdong,Xu, Chi,Meng, Xiao,Ma, Yuguo

supporting information, p. 5102 - 5107 (2014/07/08)

Unusual regio- and stereo-selectivity in Diels-Alder (D-A) reactions were achieved between bulky N-phenylmaleimides and anthracene derivatives. Using multiple substituents with steric hindrance on both diene and dienophile, a noticeable shift toward 1,4-addition was successfully obtained. The substrate scope in this reaction was broad and the highest yield of anti-1,4-adducts was over 90%. Novel structures of anti-1,4-adducts were confirmed by single crystal X-ray diffraction analysis. This study not only provides the first reported method of synthesizing anti-1,4-adducts and achieving otherwise unattainable regio- and stereo-selectivity, but also elucidates the importance of combining the steric effects of two reactants to shift products toward 1,4-adducts. Moreover, the resulting 1,4-adducts could be further functionalized through their halogen groups via carbon-carbon coupling reactions.

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