3600-24-6Relevant articles and documents
Hydrogen Sulfide Reactivity with Thiols in the Presence of Copper(II) in Hydroalcoholic Solutions or Cognac Brandies: Formation of Symmetrical and Unsymmetrical Dialkyl Trisulfides
Nedjma, Mustapha,Hoffmann, Norbert
, p. 3935 - 3938 (1996)
In the presence of copper(II), hydrogen sulfide reacts with thiols (methanethiol and ethanethiol) to yield symmetrical or unsymmetrical trisulfides (dimethyl trisulfide, diethyl trisulfide, and ethyl methyl trisulfide). In alcoholic beverages, these compounds are known for their nauseous character, reminiscent of onion smell, and for their low detection levels (dimethyl trisulfide: 0.1 μg/L). A mechanism for trisulfide formation is proposed that involves a two-step redox reaction.
Kondo,K.,Negishi,A.
, p. 1525 - 1528 (1974)
Sulfur-atom insertion into the S-S bond - Formation of symmetric trisulfides
Hou, Yihua,Abu-Yousef, Imad A.,Doung, Yen,Harpp, David N.
, p. 8607 - 8610 (2007/10/03)
The reaction of triphenylmethanesulfenyl chloride (3a) with acyclic disulfides 4 or 5 give the respective trisulfides 1 or 2 in moderate to good yield and selectivity. A mechanism is advanced to explain the chemistry.
An unexpected reaction of divinyl ether of ethylene glycol with hydrogen sulfide
Musorin, G. K.,Sedunova, O. V.,Gendin, D. V.
, p. 363 - 364 (2007/10/03)
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