360065-83-4Relevant academic research and scientific papers
Substituent effects on the amination of racemic allyl carbonates using commercially available chiral rhodium catalysts
Atallah, Timothy,Blankespoor, Ronald L.,Homan, Philip,Hulderman, Chase,Samas, Brian M.,Van Allsburg, Kurt,Vrieze, Derek C.
, p. 5795 - 5798 (2013/10/01)
In the presence of commercially available chiral rhodium catalysts, a competitive benzy lamination of racemic allyl carbonates, substituted with p-X-Ph groups, shows that the reaction proceeds faster with substituents (X) that are more electron-withdrawing. Mechanistic implications of these results are discussed.
