36029-70-6Relevant academic research and scientific papers
Niobium-catalyzed activation of CF3 group on alkene: Synthesis of substituted indenes
Fuchibe, Kohei,Atobe, Kohei,Fujita, Yukari,Mori, Keiji,Akiyama, Takahiko
supporting information; scheme or table, p. 867 - 869 (2011/01/07)
A CF3 group attached to an alkene functionality was activated by a zero-valent niobium catalyst to generate niobium alkenylcarbenoid species. The niobium carbenoid species then underwent insertion to an internal aromatic C-H σ bond to give inde
Preparation of α- or β-trifluoromethylated vinylstannanes and their cross-coupling reactions
Jeong, In Howa,Park, Young Sam,Kim, Myong Sang,Song, Yong Sup
, p. 195 - 209 (2007/10/03)
α - or β-Trifluoromethylated vinylstannanes 1, 2a, 3 and 4 were prepared form 1,1-bis(phenylthio)-2,2,3,3,3-pentafluoropropylbenzene (5) via several steps. The cross-coupling arylation reactions of 1-4 with aryl iodides bearing a bromo, methoxy, methyl, n
