36041-76-6Relevant academic research and scientific papers
Halogenation of carbonyl compounds by an ionic liquid, [AcMIm]X, and Ceric Ammonium Nitrate (CAN)
Ranu, Brindaban C.,Adak, Laksmikanta,Banerjee, Subhash
, p. 358 - 362 (2008/02/13)
An ionic liquid, acetylmethylimidazolium halide ([AcMIm]X), in combination with ceric ammonium nitrate promotes halogenations of a wide variety of ketones and 1,3-keto esters at the ?-position. The ionic liquid acts here as reagent as well as reaction medium, and thus the reaction does not require any organic solvent or conventional halogenating agent. The reaction is completely arrested when the radical quencher TEMPO is used. A plausible radical mechanism is also suggested. CSIRO 2007.
KINETICALLY DISTINCT TRIPLETS IN THE PHOTOREARRANGEMENT OF 2-PHENYLCYCLOHEXANONE TO cis- AND trans-6-PHENYL-5-HEXENALS
Wagner, Peter J.,Stratton, Thomas J.
, p. 3317 - 3322 (2007/10/02)
A reinvestigation of the photochemistry of 2-phenylcyclohexanone reveals that the two aldehyde products, cis- and trans-6-phenyl-5-hexenal, come from triplets of different lifetimes.That the two distinct triplets are not simply the two conformers with phe
Triazolocycloalkylthiadiazine derivatives
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, (2008/06/13)
Novel triazolocycloalkylthiadiazines, their preparation, and use as antisecretory agents and central nervous system depressants.
Triazolocycloalkylhydrothiadiazine derivatives
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, (2008/06/13)
Novel triazolocycloalkylhydrothiadiazines and their preparation, which are useful as antisecretory agents, central nervous system stimulants, and central nervous system depressants, are disclosed.
