36042-99-6 Usage
Uses
Used in Coordination Chemistry:
Bis(1-naphthyl)chlorophosphine is used as a phosphine ligand for the synthesis of transition metal complexes. Its strong coordinating ability allows it to form stable complexes with transition metals, which are essential in various chemical reactions and applications.
Used in Organometallic Catalysis:
In the field of organometallic catalysis, Bis(1-naphthyl)chlorophosphine serves as a crucial ligand in catalytic processes such as hydrogenation and cross-coupling reactions. Its presence enhances the catalytic activity and selectivity of the reactions, leading to more efficient and cleaner chemical transformations.
Used in Research Studies:
Due to its unique properties, Bis(1-naphthyl)chlorophosphine is widely utilized in various research studies. It helps scientists explore new reaction pathways, develop novel catalysts, and understand the underlying mechanisms of complex chemical processes.
Used in Industrial Processes:
Bis(1-naphthyl)chlorophosphine is also employed in various industrial processes, particularly in the production of pharmaceuticals, agrochemicals, and fine chemicals. Its strong coordinating ability and versatility make it an indispensable component in the synthesis of complex organic molecules and the development of efficient catalytic systems.
Check Digit Verification of cas no
The CAS Registry Mumber 36042-99-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,0,4 and 2 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 36042-99:
(7*3)+(6*6)+(5*0)+(4*4)+(3*2)+(2*9)+(1*9)=106
106 % 10 = 6
So 36042-99-6 is a valid CAS Registry Number.
InChI:InChI=1/C20H14ClP/c21-22(19-13-5-9-15-7-1-3-11-17(15)19)20-14-6-10-16-8-2-4-12-18(16)20/h1-14H
36042-99-6Relevant academic research and scientific papers
Development of efficient and reusable diarylphosphinopolystyrene-supported palladium catalysts for C-C bond forming cross-coupling reactions
Schweizer, Stephane,Becht, Jean-Michel,Le Drian, Claude
, p. 1150 - 1158 (2008/03/28)
Short and versatile syntheses of reusable diarylphosphinopolystyrene- supported palladium catalysts 3a-j are described. The bis(o-tolyl)phosphino catalyst 3b is particularly efficient for the Suzuki and Sonogashira cross-couplings, whereas the bis(m-tolyl)phosphino catalyst 3c is the most active catalyst for Heck reactions. The couplings are performed under non-anhydrous reaction conditions and require only low amounts of supported palladium (0.5 mequivs. for Suzuki-Miyaura, 1.0 mequiv. for Sonogashira and 0.5 mequivs. for Heck reactions could be sufficient). Catalysts 3a-j are recovered by filtration and can be reused more than four times with no loss of efficiency.
