36069-05-3 Usage
Description
This alkaloid has been found in both Veratrum album and V. viride Ait. It
crystallizes from EtOH in hexagonal tablets and has [α]20D - 139° (CHC13). The
hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also
crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five
replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)-
glucose and isojervine, an isomer of jervine. This latter base crystallizes with
solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with
EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]20D -
32° (EtOH).
References
Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)
Check Digit Verification of cas no
The CAS Registry Mumber 36069-05-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,0,6 and 9 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 36069-05:
(7*3)+(6*6)+(5*0)+(4*6)+(3*9)+(2*0)+(1*5)=113
113 % 10 = 3
So 36069-05-3 is a valid CAS Registry Number.
InChI:InChI=1/C33H49NO8/c1-15-11-22-26(34-13-15)17(3)33(42-22)10-8-20-21-6-5-18-12-19(40-31-30(39)29(38)27(36)23(14-35)41-31)7-9-32(18,4)25(21)28(37)24(20)16(33)2/h5,15,17,19-23,25-27,29-31,34-36,38-39H,6-14H2,1-4H3/t15?,17?,19-,20?,21?,22+,23?,25?,26-,27+,29?,30?,31+,32?,33-/m0/s1
