36069-80-4Relevant academic research and scientific papers
Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides
Bi, Wen-Zhu,Zhang, Wen-Jie,Li, Zi-Jie,He, Yuan-Hao,Feng, Su-Xiang,Geng, Yang,Chen, Xiao-Lan,Qu, Ling-Bo
, p. 8701 - 8705 (2021/10/22)
A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides
Chen, Jie,Mao, Jincheng,He, Yue,Shi, Daqing,Zou, Binyang,Zhang, Guoqi
supporting information, p. 9496 - 9500 (2015/11/18)
AlCl3-promoted thiolation of acyl C-H bonds with arylsulfonyl hydrazides was developed, which represents an effective synthesis of S-aryl thiocarbamates via C-S bond formation reaction.
Palladium-catalyzed insertion reactions of isocyanides into thiocarbamates and selenocarbamates
Shiro, Daisuke,Fujiwara, Shin-Ichi,Tsuda, Susumu,Iwasaki, Takanori,Kuniyasu, Hitoshi,Kambe, Nobuaki
supporting information, p. 465 - 467 (2015/05/20)
The insertion reaction of isocyanides with thiocarbamates and selenocarbamates in the presence of a Pd(0) catalyst to selectively give 2-oxoethanimidothioates and -selenoates is reported. This is the first example of the insertion of an isocyanide into a
REACTIONS OF UNSTABLE DIALKYLCARBAMOYL LITHIUMS WITH SULFUR COMPOUNDS
Mizuno, Takumi,Nishiguchi, Ikuzo,Hirashima, Tsuneaki
, p. 2403 - 2412 (2007/10/02)
Unstable dialkylcarbamoyl lithiums, generated from the reaction of lithium dialkylamides with carbon monoxide, were successfully trapped by sulfur compounds (elemental sulfur, disulfides, carbon disulfide, and carbonyl sulfide) at low temperature, through their potent affinity with a sulfur atom.These efficient reactions were also applied to development of a facile synthetic method for thiocarbamates, useful herbicides, and thiooxamates.
