360783-60-4

Basic information

• Product Name: H₃NC₆H₁₀NH₃⁽²⁺⁾*Mn₂(HPO₄)2(C₂O₄)(H₂O)2^(2-)=(H₃NC₆H₁₀NH₃)(Mn₂(HPO₄)2(C₂O₄)(H₂O)2)
• CAS NO: 360783-60-4
• Molecular Weight: 542.091
• Mol File: 360783-60-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: H₃NC₆H₁₀NH₃⁽²⁺⁾*Mn₂(HPO₄)2(C₂O₄)(H₂O)2^(2-)=(H₃NC₆H₁₀NH₃)(Mn₂(HPO₄)2(C₂O₄)(H₂O)2)(CAS DataBase Reference)
• NIST Chemistry Reference: H₃NC₆H₁₀NH₃⁽²⁺⁾*Mn₂(HPO₄)2(C₂O₄)(H₂O)2^(2-)=(H₃NC₆H₁₀NH₃)(Mn₂(HPO₄)2(C₂O₄)(H₂O)2)(360783-60-4)
• EPA Substance Registry System: H₃NC₆H₁₀NH₃⁽²⁺⁾*Mn₂(HPO₄)2(C₂O₄)(H₂O)2^(2-)=(H₃NC₆H₁₀NH₃)(Mn₂(HPO₄)2(C₂O₄)(H₂O)2)(360783-60-4)

Safety Data

• Hazardous Substances Data: 360783-60-4(Hazardous Substances Data)

Upstream product

• 13598-36-2 phosphonic Acid 
• 2615-25-0 trans-1,4-cyclohexyldiamine 
• 89087-78-5 manganese(II) oxalate dihydrate 

Relevant articles and documents

Synthesis, structural relationships and magnetic properties of new amine-templated manganese(II) phosphate oxalate framework materials

Three novel three-dimensional framework materials in the manganese(II)-phosphate-oxalate system have been prepared hydrothermally using organic amines as structure-directing agents. [H3NC6H10NH3][Mn2(HPO 4)2(C2O4)-(H2O)2 ] 1 and [H3N(CH2)2NH3][Mn2(HPO 4)2(C2O4)(H2O)2 ] 2 have related, but not isomorphous, structures based on layers of vertex-sharing MnO6, and PO4 polyhedra linked by bridging oxalate groups. [H3N(CH2)2NH3][Mn4(HPO 4)2-(C2O4)3(H2 O)2]·2H2O 3 has a very different structure composed of edge-sharing dimeric MnO6 units linked into chains by PO4 groups, and into a 3-D framework by oxalate units. 3 can be topotactically dehydrated, with loss of both extra-framework and co-ordinated water, to produce a new phase 4. The magnetic susceptibilities of phases 1, 3 and 4 all show Curie-Weiss behaviour above about 50 K, and a maximum in the susceptibility curve in the vicinity of 7-12 K, indicating significant antiferromagnetic exchange. Structural relationships to other phosphate-oxalate frameworks are discussed.