36093-33-1Relevant academic research and scientific papers
METAL COMPLEX, AND METHOD FOR SYNTHESIS OF NITROGEN-CONTAINING ORGANIC COMPOUND USING METAL COMPLEX
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Paragraph 0098-0099, (2017/04/29)
PROBLEM TO BE SOLVED: To provide a method that synthesizes a nitrogen-containing organic compound under a relatively mild condition and in a relatively simple process. SOLUTION: A method that synthesizes a nitrile compound includes a step for the reaction between an acid chloride and a complex represented by formula (1A) or formula (1B) (M1-M7 independently represent Ti, Zr, Hf, V, or the like; L1-L7 independently represent a ligand comprising a substituted/unsubstituted cyclopentadienyl derivative, a diphenylamine ligand or the like). SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
Ring Transformation Equilibrium (Bond Switch) in the 5-(2-Aminovinyl)isothiazole System via Hypervalent Sulfurane. Synthesis, Structure Determination, and Kinetic Study
Akiba, Kin-ya,Kashiwagi, Kohichi,Ohyama, Yoshihiko,Yamamoto, Yoshuke,Ohkata, Katsuo
, p. 2721 - 2730 (2007/10/02)
Reaction of 3-aryl-5-methylisothiazoles (4) with aromatic nitriles afforded the adducts 3, 5-(2-amino-2-arylvinyl)-3-arylisothiazole derivatives, in the presence of LDA.By employing p-chlorobenzonitrile-15N, the presence of ring transformation from one is
