36093-35-3Relevant academic research and scientific papers
Zirconium-mediated conversion of amides to nitriles: A surprising additive effect
Ruck, Rebecca T.,Bergman, Robert G.
, p. 5375 - 5377 (2004)
Chloride coordination is the key: Dimethylzirconocene reacts with amides to form methylzirconium amide complexes. On heating, in the presence of a chloride source, these compounds are converted into N-acylimidozirconocene complexes that react intramolecularly to form the corresponding nitrile compounds (see scheme; Cp = C5H5). Mechanistic studies reveal that chloride coordination to zirconium is required for this transformation to occur.
METAL COMPLEX, AND METHOD FOR SYNTHESIS OF NITROGEN-CONTAINING ORGANIC COMPOUND USING METAL COMPLEX
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Paragraph 0098-0099, (2017/04/29)
PROBLEM TO BE SOLVED: To provide a method that synthesizes a nitrogen-containing organic compound under a relatively mild condition and in a relatively simple process. SOLUTION: A method that synthesizes a nitrile compound includes a step for the reaction between an acid chloride and a complex represented by formula (1A) or formula (1B) (M1-M7 independently represent Ti, Zr, Hf, V, or the like; L1-L7 independently represent a ligand comprising a substituted/unsubstituted cyclopentadienyl derivative, a diphenylamine ligand or the like). SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
13C and 15N Chemical Shift Tensors of Para-Substituted Benzonitriles
Sardashti, Maziar,Maciel, Gary E.
, p. 4620 - 4632 (2007/10/02)
The principal elements of the 13C and 15N chemical shift tensors of a series of 10 para-substituted benzonitriles, enriched in 15N, have been determined.For the 15N case the static powder patterns spinning sideband methods have been employed and compared.
