36103-65-8Relevant articles and documents
Intermolecular transfer of triarylsilane from RhCl(H)(SiAr3)[P(i-Pr)3]2 to a platinum(0) complex, giving cis-PtH(SiAr3)(PEt3)2 (Ar = C6H5, C6H4F-p, C6H4Cl-p)
Koizumi, Take-Aki,Osakada, Kohtaro,Yamamoto, Takakazu
, p. 6014 - 6016 (2008/10/08)
Chlorohydrido(triarylsilyl)rhodium(III) complexes RhCl(H)(SiAr3)[P(i-Pr)3]2 (1a, Ar = C6H5; 1b, Ar = C6H4F-p; 1c, Ar = C6H4Cl-P) react with Pt(PEt3]4 to give mixtures of cis-PtH(SiAr3)(PEt3)2 (2a, Ar = C6H5; 2b, Ar = C6H4F-p; 2c, C6H4Cl-P) and RhCl(PEt3)3. Complexes 2a-c have been characterized by X-ray crystallography and/or NMR spectroscopy.