361211-84-9Relevant academic research and scientific papers
Synthesis and characterization of unbridged metallocene dichloride complexes with two differently mono-substituted indenyl ligands and their application as catalysts for the polymerization of ethene and propene
Schmidt, Roland,Deppner, Matthias,Alt, Helmut G
, p. 43 - 65 (2008/10/08)
The synthesis of unbridged metallocene dichloride complexes of the type Ind#Ind′ZrCl2 (Ind# = 2-arylalkyl-substituted indenyl, Ind′ = 1-ω-alkenyl-substituted or 2-alkyl-substituted indenyl) is described. The complexes are characterized by 1H and 13C NMR spectroscopy and mass spectrometry and tested for the catalytic polymerization of ethene and propene. The polymerization results and the polymer properties indicate a considerable influence of the catalyst structure on the polymerization behavior.
