36132-68-0

Upstream product

• 17797-15-8 1-(p-Tolyl)-cyclohexylamin 
• 117781-59-6 Cyclohex-1-enyl-p-tolyl-amine 
• 108-94-1 cyclohexanone 
• 106-49-0 p-toluidine 

Downstream Products

• 31003-21-1 (1-p-Tolylamino-cyclohexyl)-phosphonic acid dimethyl ester 
• 33524-12-8 (1-p-Tolylamino-cyclohexyl)-phosphonic acid diethyl ester 
• 145182-02-1 (1-p-Tolylamino-cyclohexyl)-phosphonic acid diisobutyl ester 
• 145182-01-0 (1-p-Tolylamino-cyclohexyl)-phosphonic acid dibutyl ester 
• 91029-25-3 Cyclohexane-spiro-2-<1-(p-tolyl)-3-methoxycarbonyl-4-(p-tolyl)-carbamoyl-3-azetine> 
• 91029-18-4 trans-N-(Cyclohexen-1-yl)-N-(1,2-dimethoxycarbonylvinyl)-p-toluidine 
• 91029-20-8 cis-N-(Cyclohexen-1-yl)-N-(1,2-dimethoxycarbonylvinyl)-p-toluidine 
• 1133274-41-5 C₁₇H₂₁NO₃S 
• 87261-67-4 2-[(N-cyclohexyl-4-methylanilino)methyl]-4,5-dihydro-1H-imidazole 
• 153396-93-1 1,2,3,4-tetrahydro-4,6-dimethylspiro 
• 153397-03-6 1-allyl-1-(p-tolylamino)cyclohexane 
• 117781-65-4 2-(β-cyanoethyl)cyclohexanone p-methylanil 
• 145182-00-9 (1-p-Tolylamino-cyclohexyl)-phosphonic acid dipropyl ester 
• 145182-03-2 (1-p-Tolylamino-cyclohexyl)-phosphonic acid bis-(3-methyl-butyl) ester 

Relevant academic research and scientific papers

Oxidative Rearrangement of Primary Amines Using PhI(OAc)2 and Cs2CO3

An oxidative rearrangement of primary amines mediated by a hypervalent iodine(III) reagent is herein reported. The combination of PhI(OAc)2 and Cs2CO3 proves highly efficient at inducing the direct 1,2-C to N migration of primary amines, which can be applied to the preparation of both acyclic and cyclic amines. A mechanistic study shows that the rearrangement proceeds via a concerted mechanism.

Synthesis of 3-Sulfonylamino Quinolines from 1-(2-Aminophenyl) Propargyl Alcohols through a Ag(I)-Catalyzed Hydroamination, (2 + 3) Cycloaddition, and an Unusual Strain-Driven Ring Expansion

We describe herein a silver-catalyzed conversion of 1-(2-aminophenyl)-propargyl alcohols to 4-substituted 3-tosylaminoquinolines using TsN3 as an amino surrogate. Controlled reactions reveal the pathway consisting of Ag(I)-catalyzed 5-exo-dig cyclization, catalyst-free (2 + 3) cycloaddition, and ring-expansive rearrangement via nitrogen expulsion. As a support study, we show that the cyclic enamines in similar conditions produce amidines via a C - C bond migration. (Chemical Equation Presented).

Transition Metal Complexes and Preparation Methods Thereof

The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound accord

Synthesis and nematicidal activity of 2-(1H-benzo[d]imidazol-2-ylmethyl)-4- aryl-1-thia-4-azaspiro[4.5]decan-3-one

A series of N-cyclohexylidene-N-phenylamines 3 are prepared by the condensation of cyclohexanone 1 with aryl amine 2, subsequent treatment of 3 with thiomalic acid give the corresponding 2-(3-oxo-4-aryl-1-thia-4-azaspiro[4. 5]dec-2-yl)acetic acid 4, which

CATALYST COMPOSITION COMPRISING GROUP 4 TRANSITION METAL COMPLEXES AND METHOD FOR PREPARING POLYOLEFINS USING THE SAME

The present invention relates to a catalyst composition comprising a novel structure of a Group 4 transition metal compound, to a method for preparing the same, and to a method for preparing a polyolefin using the catalyst composition. The method for prep

TRANSITION METAL COMPLEXES AND PREPARATION METHODS THEREOF

The present invention provides a novel mononuclear transition metal compound, a novel binuclear transition metal compound, a novel organic amine or phosphorous compound, and a method for preparing the same. The mononuclear transition metal compound accord

Method for preparing aromatic secondary amino compound

Disclosed are (1) a method for preparing an aromatic secondary amino compound which comprises reacting an N-cyclohexylideneamino compound in the presence of a hydrogen moving catalyst and a hydrogen acceptor by the use of a sulfur-free polar solvent and/or a cocatalyst, and (2) a method for preparing an aromatic secondary amino compound which comprises reacting cyclohexanone or a nucleus-substituted cyclohexanone, an amine and a nitro compound corresponding to the amine in a sulfur-free polar solvent in the presence of a hydrogen moving catalyst, a cocatalyst being added or not added. In a further aspect, a method is provided for the preparation of aminodiphenylamine by reacting phenylenediamine and cyclohexanone in the presence of a hydrogen transfer catalyst in a sulfur-free polar solvent while using nitroaniline as a hydrogen acceptor.

Radical cyclisations of imines and hydrazones

Radical cyclisation of sp3 carbon-centred radicals onto imines and hydrazones provides a new method for the synthesis of 5- and 6-membered ring nitrogen heterocycles. Cyclisation onto the electrophilic carbon of the C=N group and 5-exo stereoelectronic selectivity are the dominating mechanistic parameters. The C-centred radical intermediates were generated from benzeneselenyl precursors using Bu3SnH.

SYNTHESIS AND NITRATION OF 4,6(4,8)-DIMETHYL-4-METHYL-6(8)-METHOXY-1,2,3,4-TETRAHYDROSPIRO

The cyclization of 1-allyl-1-arylaminocyclohexanes under conditions of acid catalysis afforded 1,2,3,4-tetrahydro-4-methylspiro methyl (methoxy)-substituted in the phenylene ring.Their mono- and dinitro derivatives were synthesiz

Imine-enamine tautomerism in the anils of cyclohexanone and 2-(β-cyanoethyl)cyclohexanone

The products from the condensation of cyclohexanone and 2-(β-cyanoethyl)cyclohexanone with para- and ortho-disubstituted anilines in 10percent solutions in carbon tetrachloride exist as mixtures of the imine and enamine tautomers.The tautomeric compositio