361447-42-9

Basic information

• Product Name: (E)-1-(2-Phenylvinyl)-1-cyclopentanecarbaldehyde
• Synonyms: (E)-1-(2-Phenylvinyl)-1-cyclopentanecarbaldehyde
• CAS NO: 361447-42-9
• Molecular Weight: 200.28
• Mol File: 361447-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-1-(2-Phenylvinyl)-1-cyclopentanecarbaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-(2-Phenylvinyl)-1-cyclopentanecarbaldehyde(361447-42-9)
• EPA Substance Registry System: (E)-1-(2-Phenylvinyl)-1-cyclopentanecarbaldehyde(361447-42-9)

Safety Data

• Hazardous Substances Data: 361447-42-9(Hazardous Substances Data)

Upstream product

• 361447-40-7 (E)-Methyl 1-(2-phenylvinyl)-1-cyclopentanecarboxylate 
• 91083-82-8 (E)-methyl 4-phenylbut-3-enoate 
• 2243-53-0 trans-styrylacetic acid 
• 361447-41-8 (E)-1-Hydroxymethyl-1-(2-phenylvinyl)cyclopentane 

Relevant articles and documents

New results on the triplet photoreactivity of β,γ-unsaturated aldehydes: Diastereoselective synthesis of cyclopropanecarbaldehydes

A comparative study on the triplet photoreactivity of a series of β,γ-unsaturated aldehydes and methyl ketones has been carried out. Aldehydes 14 and 20 were found to undergo the oxa-di-π-methane rearrangement yielding the corresponding cyclopropane carbaldehydes 15 and 21 diastereoselectively. Decarbonylations and 1,3-carbonyl migrations have been observed in some cases, although these reactions do not take place via a Norrish Type I mechanism.