361522-14-7

Basic information

• Product Name: tert-Butyl-((1R,4R,5S,8S,11S)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-6-en-11-ylmethoxy)-diphenyl-silane
• CAS NO: 361522-14-7
• Molecular Weight: 532.795
• Mol File: 361522-14-7.mol

Chemical Properties

• CAS DataBase Reference: tert-Butyl-((1R,4R,5S,8S,11S)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-6-en-11-ylmethoxy)-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: tert-Butyl-((1R,4R,5S,8S,11S)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-6-en-11-ylmethoxy)-diphenyl-silane(361522-14-7)
• EPA Substance Registry System: tert-Butyl-((1R,4R,5S,8S,11S)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-6-en-11-ylmethoxy)-diphenyl-silane(361522-14-7)

Safety Data

• Hazardous Substances Data: 361522-14-7(Hazardous Substances Data)

Upstream product

• 361521-91-7 (1S,2R,4aR,5S)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1-[1,3]dioxolan-2-yl-1,2-dimethyl-7-oxo-1,3,4,5,6,7-hexahydro-2H-naphthalene-4a-carbonitrile 
• 361521-89-3 (3R,4R)-3-(1,3-dioxolan-2-yl)-3,4-dimethyl-2-oxo-cyclohexanecarbonitrile 
• 361522-05-6 (1R,4R,5S,8S,11S)-11-(tert-Butyl-diphenyl-silanyloxymethyl)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-6-en-10-ol 

Downstream Products

• 361522-07-8 tert-Butyl-((1S,4R,5S,6S,8R,11S)-5-[1,3]dioxolan-2-yl-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodec-11-ylmethoxy)-diphenyl-silane 
• 361522-49-8 (1S,4R,5S,6S,8R,11S)-11-(tert-Butyl-diphenyl-silanyloxymethyl)-4,5-dimethyl-9-oxa-tricyclo[6.2.2.0^1,6]dodecane-5-carbaldehyde 

Relevant articles and documents

The enantioselective synthesis of key intermediates for the synthesis of (+)-brevifloralactone from R-(-)-carvone

Starting from R-(-)-carvone, a sequence of reactions has been developed for the enantioselective synthesis of key intermediates, which contain ether and hemiacetal bridges that are present in antifeedant clerodanes such as brevifloralactone and jodrellin.