361522-86-3Relevant academic research and scientific papers
New routes for preparation and characterization of [Au2(C=N) 2P(Ph)2CH2P(Ph)2] complex
Jaafar, Mohammed H.,Al-Ohaly
, p. 642 - 644 (2013)
The gold complex i.e., [Au2(C=N)2P(Ph) 2CH2P(Ph)2] has been successfully produced by three reactions, the reaction of polymeric gold cyanide [Au(CN)]n with a suspension of bis(diphenylphosphino)methane (dppm), in acetone in a 2:1, pure ammonia (NH3), [Au(C=N)]n and (Ph)2PCH2P(Ph) 2 in acetone in a 2:2:1 or that of [Au(C=N)(NH3) 2] with (Ph)2PCH2P(Ph)2 in acetone in a 1:0.5 giving a white precipitate collected as Au2(C=N) 2P(Ph)2CH2P(Ph)2. The complex was characterized by elemental analysis, FT-IR and NMR spectroscopy and found in agreement with the proposed formula C27H22N 2P2Au2.
Polymers and rings in gold(I) diphosphine complexes: Linking gold rings through aurophilic interactions
Brandys,Puddephatt
, p. 1280 - 1281 (2007/10/03)
Gold(I) complex cations of empirical formula Au[Ph2P(CH2)nPPh2]+ crystallize as rings [Au2{Ph2P(CH2)n PPh2}2]2+ when n = 3
