361543-99-9

Basic information

• Product Name: (2,6-DIMETHYL-4-METHOXYPHENYL)BORONIC ACID
• Synonyms: CHEMBRDG-BB 4006153;2,6-DIMETHYL-4-METHOXYBENZENEBORONIC ACID;(2,6-DIMETHYL-4-METHOXYPHENYL)BORONIC ACID;AKOS BRN-0095;4-Methoxy-2,6-dimethylphenylboronic acid;Boronic acid,B-(4-methoxy-2,6-dimethylphenyl)-;4-Methoxy-2,6-diMethylbenzeneboronic acid, 95%;4-Borono-3,5-dimethylanisole, 2-Borono-5-methoxy-m-xylene
• CAS NO: 361543-99-9
• Molecular Formula: C₉H₁₃BO₃
• Molecular Weight: 180.01
• Product Categories: blocks;BoronicAcids
• Mol File: 361543-99-9.mol
• Article Data: 6

Chemical Properties

• Melting Point: 168-172°C
• Boiling Point: 346.3 °C at 760 mmHg
• Flash Point: 163.2 °C
• Appearance: /
• Density: 1.11 g/cm³
• Vapor Pressure: 2.2E-05mmHg at 25°C
• Refractive Index: 1.517
• Storage Temp.: Keep Cold
• PKA: 9.11±0.58(Predicted)
• Water Solubility: Slightly soluble in water.
• CAS DataBase Reference: (2,6-DIMETHYL-4-METHOXYPHENYL)BORONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-DIMETHYL-4-METHOXYPHENYL)BORONIC ACID(361543-99-9)
• EPA Substance Registry System: (2,6-DIMETHYL-4-METHOXYPHENYL)BORONIC ACID(361543-99-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-60-37
• HazardClass: IRRITANT
• Hazardous Substances Data: 361543-99-9(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 361543-99-9 differently. You can refer to the following data:
1. suzuki reaction
2. 4-Methoxy-2,6-dimethylbenzeneboronic acid is used as pharmaceutical intermediate.

InChI:InChI=1/C9H13BO3/c1-6-4-8(13-3)5-7(2)9(6)10(11)12/h4-5,11-12H,1-3H3

Upstream product

• 5419-55-6 Triisopropyl borate 
• 6267-34-1 2-bromo-5-methoxy-1,3-dimethyl-benzene 
• 7463-51-6 4-bromo-3,5-dimethylphenol 
• 1208459-72-6 2-(4-methoxy-2,6-dimethylphenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane 
• 121-43-7 Trimethyl borate 
• 7732-18-5 water 

Downstream Products

• 851756-92-8 6-(4-methoxy-2,6-dimethyl-phenyl)-8-methyl-2-phenylamino-8H-pyrido[2,3-d]pyrimidin-7-one 
• 1028330-91-7 C₃₁H₃₄N₂O₂ 
• 1056700-85-6 2-(4-methoxy-2,6-dimethylphenyl)-9-[6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline 
• 1056700-87-8 2-(4-methoxy-2,6-dimethylphenyl)-9-[5-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline 
• 1056700-89-0 2-(4-methoxy-2,6-dimethylphenyl)-9-[4-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline 
• 1056700-91-4 8-(4-methoxy-2,6-dimethylphenyl)-2-(6-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl)-1,10-phenanthroline 
• 1056700-99-2 7-(4-methoxy-2,6-dimethylphenyl)-2-[5-(4-methoxy-2,6-dimethylphenyl)-pyridin-2-yl]-1,10-phenanthroline 
• 1392512-42-3 C₁₈H₁₇NO 
• 1392512-39-8 C₂₃H₂₀O 
• 866416-39-9 2-[4-(3,5-dimethyl-pyridin-4-yl)-3,5-dimethyl-phenyl]-malononitrile 

Relevant articles and documents

Trigonal rigid triphenols: Self-assembly and multicomponent lattice inclusion

The sterics introduced via methyl groups impart rigidity and inclusion behavior to trigonal C3-symmetric triphenol hosts H1-H4. Triphenol H1 is found to mimic the O-H...O hydrogen-bonded self-assembly of trimesic acid to yield porous honeycomb nets. It is found that 18-crown-6?H1 in turn binds guest molecules in the hexagonal voids to yield guest?guest?host multicomponent molecular crystals. The triphenol H2 and the homologous derivatives H3 and H4 are also found to crystallize with 18-crown-6 and other guests to yield multicomponent crystals, but in these cases the 18-crown-6 is found to serve as a spacer. While the structure of H2 is determined in its guest-free form, some of the inclusion compounds of triphenols lend themselves to crystal packings that are deciphered based on network topologies. The networks observed for H1-Tol and H3-C-B-Et are unique; in the latter, the crystal packing analysis reveals organization of molecules into a pattern that is reminiscent of borromean rings.

Syntheses of extreme sterically hindered 4-methoxyboronic acids

4-Iodoanisoles 3a,b, 3d and 4-bromoanisoles 4a-d were readily obtained. An extreme steric hindrance precluded obtaining 3c. Catalytic borylation of 3a,b, 3d followed by hydrolysis of boronic ester 26a,b, 26d easily provided the boronic acids 5a,b, 5d. Com

Ultralarge hyperpolarizability twisted π-electron system electro-optic chromophores: Synthesis, solid-state and solution-phase structural characteristics, electronic structures, linear and nonlinear optical properties, and computational studies

This contribution details the synthesis and chemical/physical characterization of a series of unconventional twisted π-electron system electro-optic (EO) chromophores. Crystallographic analysis of these chromophores reveals large ring-ring dihedral twist