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(1R,2R,3S)-2-Phenyl-3-vinyl-cyclopropanecarboxylic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

361979-85-3

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361979-85-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 361979-85-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,6,1,9,7 and 9 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 361979-85:
(8*3)+(7*6)+(6*1)+(5*9)+(4*7)+(3*9)+(2*8)+(1*5)=193
193 % 10 = 3
So 361979-85-3 is a valid CAS Registry Number.

361979-85-3Upstream product

361979-85-3Relevant academic research and scientific papers

Highly diastereoselective synthesis of vinylcyclopropane derivatives with (-)-8-phenylmenthol as chiral auxiliary

Ye,Tang,Dai

, p. 5717 - 5722 (2001)

The silylated telluronium allylide 4, generated in situ from the corresponding telluronium salt in the presence of LiTMP, reacted with (-)-8-phenylmenthyl α,β-unsaturated esters to afford trans-2-silylvinyl-trans-3-substituted cyclopropyl esters with high diastereoselectivity in high yields. The absolute configuration was determined by chemical transformation. A mechanistic rationale is proposed.

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