362-95-8

Basic information

• Product Name: 1-(azido(phenyl)methyl)-4-fluorobenzene
• Synonyms: 1-(azido(phenyl)methyl)-4-fluorobenzene
• CAS NO: 362-95-8
• Molecular Weight: 227.241
• Mol File: 362-95-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(azido(phenyl)methyl)-4-fluorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(azido(phenyl)methyl)-4-fluorobenzene(362-95-8)
• EPA Substance Registry System: 1-(azido(phenyl)methyl)-4-fluorobenzene(362-95-8)

Safety Data

• Hazardous Substances Data: 362-95-8(Hazardous Substances Data)

Upstream product

• 459-57-4 4-fluorobenzaldehyde 
• 100-58-3 phenylmagnesium bromide 
• 149099-27-4 4-fluorobenzhydrol 
• 345-83-5 4-fluorobenzophenone 

Relevant articles and documents

Highly selective direct azidation of alcohols over a heterogeneous povidone-phosphotungstic solid acid catalyst

A simple protocol for the selective azidation of alcohols is developed using a solid acid hybrid of a povidone and phosphotungstic acid (PVP-PWA) using azidotrimethylsilane as an azide source at room temperature. In a broad substrate scope, various activated as well as unactivated benzylic and diphenyl alcohols were treated smoothly with TMS-N3 to selectively produce only azide products with excellent yields in a very short reaction time of 2 h. FT-IR confirmed the stability of the catalyst with retention of the Keggins structure after the reaction. Recycling experiments demonstrated the reusability of the PVP-PWA (3?:?1) several times without losing its original activity.