36206-75-4Relevant academic research and scientific papers
Molecular complexity via C-H activation: A dehydrogenative Diels-Alder reaction
Stang, Erik M.,White, M. Christina
supporting information; experimental part, p. 14892 - 14895 (2011/11/01)
Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-sulfoxide- catalyzed dehydrogenative Diels-Alder reaction that converts simple terminal olefins into complex cycloadducts in a single operation.
SYNTHESIS OF SORBIC ALCOHOL (2E,4E-HEXADIEN-1-OL)
Vasil'ev, A. A.,Poddubnaya, S. S.,Cherkaev, G. V.,Cherkaev, V. G.
, p. 1457 - 1460 (2007/10/02)
The decomposition of 1-acetoxy-3-acetoxymethoxy-4-hexene by the action of acids leads to a 1:2 mixture of 1-acetoxy-2,4-hexadiene and 1-acetoxy-3,5-hexadiene.The same compounds are formed in a ratio of 1:1 during the pyrolysis of 1,3-diacetoxy-4-hexene.
