36233-77-9

Upstream product

• 2749-94-2 1-methoxy-4-(prop-1-yn-1-yl)benzene 

Downstream Products

• 2749-94-2 1-methoxy-4-(prop-1-yn-1-yl)benzene 
• 78035-04-8 1-Methoxy-4-(2,3,4-trimethyl-cyclobut-1-enyl)-benzene 
• 121-97-1 4-Methoxypropiophenone 
• 78034-99-8 8-(4-Methoxy-phenyl)-7-methyl-bicyclo[4.2.0]oct-1⁽⁸⁾-ene 
• 78035-02-6 7-(4-Methoxy-phenyl)-8-methyl-bicyclo[4.2.0]oct-7-ene 
• 78035-06-0 1-[(Z)-1-(2-Fluoro-cyclohexyl)-propenyl]-4-methoxy-benzene 
• 98386-72-2 3,5-Diethoxy-1-(4-methoxyphenyl)-6-methyl-1-cyclohexen 
• 36233-78-0 (Z)-1-Bromo-1-(4-methoxyphenyl)-1-propene 
• 78035-01-5 6-(4-Methoxy-phenyl)-7-methyl-bicyclo[3.2.0]hept-6-ene 
• 78035-05-9 1-[(Z)-1-(2-Fluoro-cyclopentyl)-propenyl]-4-methoxy-benzene 
• 78035-00-4 9-(4-Methoxy-phenyl)-8-methyl-bicyclo[5.2.0]non-1⁽⁹⁾-ene 
• 78035-03-7 8-(4-Methoxy-phenyl)-9-methyl-bicyclo[5.2.0]non-8-ene 

Relevant academic research and scientific papers

Cycloadditions of 1-(4-Methoxyphenyl)-2-methylvinyl Cation to Olefins. Stereochemistry and Structure of the Reaction Products

(E)-1-Bromo-1-(4-methoxyphenyl)-1-propene (1a) reacts stereospecifically with (Z)-2-butene and silver tetrafluoroborate by cycloaddition of the intermediate vinyl cation 2a to give cis-1-(4-methoxyphenyl)-2,3,4-trimethyl-1-cyclobutene (3); with (E)-2-butene, 3 and trans-1-(4-methoxyphenyl)-2,3,4-trimethyl-1-cyclobutene (4) are formed in a ratio of 1:4.These results are in accord with a synchronous cycloaddition of the vinyl cation 2a to (Z)- and (E)-2-butene.Cyclohexene derivatives 14a, 14b, and 14c are obtained predominantly by the reaction of 1a and AgBF4 or AgSbF6 with vinylcyclopropane (11), ethyl vinyl ether (12), and isobutene (13), respectively.