362598-91-2Relevant academic research and scientific papers
Structure and reactivity of the cationic nickel compound [(η3:η1-Ind(CH2)2 NMe2)Ni(PPh3)][BPh4]
Groux, Laurent F.,Zargarian, Davit
, p. 3811 - 3817 (2001)
The solid-state structure of the first nickel compound containing a chelating amino-indenyl ligand, [(η3:η1-Ind(CH2)2 NMe2)Ni(PPh3)][BPh4] (2), has been resolved and confirms the chelation of the amine tether to the nickel center. Complex 2 acts as a precatalyst for the oligomerization of norbornene, the dimerization of phenylsilane, and the polymerization of styrene. The results of these catalytic reactions are qualitatively different from those catalyzed by the cationic species generated in situ from the precursor complex (η3:η0-Ind(CH2)2 NMe2)Ni(PPh3)Cl (1). Phosphines displace the amine tether in 2 to give the bis-(phosphine) cations [(η3:η0-Ind(CH2)2 NMe2)Ni(Ph2PCH2CH2 PPh2)]+ (3) and [(η3:η0- Ind(CH2)2NMe2)Ni(PPh3) (PR3)]+ (4, R = Ph; 5, R = Me), whereas LiI reacts to form the neutral compound [(η3:η0- Ind(CH2)2NMe2)Ni(PPh3)I]· LiBPh4 (7). displacement of the amine tether by pyridine and its methyl-substituted derivatives leads to an equilibrium between 2 and [(η3:η0-Ind(CH2)2 NMe2)Ni(PPh3)L]+ (6) with Keq values of 9 (6a, L = pyridine), 2.0 (6b, L = 2-picoline), 23 (6c, L = 3-picoline), 33 (6d, L = 4-picoline), and 16 (6e, L = 3,5-lutidine).
