36262-59-6Relevant academic research and scientific papers
Succinimide-Promoted Malonylamination of Alkenes with Amines and Iodonium Ylides via Trapping of Transient Aminium Radical Cations
Zhang, Liang,Kong, Xiangjin,Liu, Shuya,Zhao, Zhiguo,Yu, Qun,Wang, Wei,Wang, Yao
, p. 2923 - 2926 (2019)
A conceptually distinct strategy enabling malonylamination of alkenes with abundant amines and iodonium ylides without assistance of any transition metal was developed. Succinimide was identified as a proton shuttle that can not only largely accelerate the process of trapping highly unstable radical ion pairs with alkenes but also significantly improve the chemical yields.
A novel intermolecular synthesis of γ-lactones via visible-light photoredox catalysis
Wei, Xiao-Jing,Yang, Deng-Tao,Wang, Lin,Song, Tao,Wu, Li-Zhu,Liu, Qiang
supporting information, p. 6054 - 6057 (2014/01/06)
Direct γ-lactone formation via visible-light photoredox catalysis has been achieved efficiently including hydroxylalkylation of aromatic alkenes and transesterification. The present photocatalytic protocol has good regioselectivity and substrate compatibility, affording a novel way to intermolecular γ-lactone synthesis by the reaction of styrenes with α-bromo esters in the absence of any external oxidants.
