362632-52-8Relevant academic research and scientific papers
Reactivity studies of (η6-p-cymene) ruthenium complexes with 4,4′-bipyridine and imidazole ligands
Rao,Sarkhel
, p. 760 - 762 (2007/10/03)
Reactions of [(η6-p-cymene)RuCl2]2, (a), [(η6-pcymene)Ru(EPh3)Cl2] {E = P (b) or As (c)} with 4,4′-bipyridine yielded bridged complexes of the type [(η6-p-cymene)RuCl2-μ-4, 4′-bipy-Cl2Ru(η6-p-cymene)] (1) and [(η6-p-cymene)RuCl(EPh3)-μ-4,4′-bipy- Cl(EPh3)Ru(η6-p-cymene)] {E=P, (2); As, (3)} respectively. Complex (b) with imidazole in the presence of NaBF4 in methanol gave compound of the type [(η6-pcymene)Ru(PPh3)(im)Cl]BF4 (4) (im = imidazole). These complexes have been characterized with various spectroscopic techniques.
