36294-16-3

Basic information

• Product Name: Phenol, 3-methyl-, potassium salt
• CAS NO: 36294-16-3
• Molecular Formula: C7H8O.K
• Molecular Weight: 146.23
• Mol File: 36294-16-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenol, 3-methyl-, potassium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 3-methyl-, potassium salt(36294-16-3)
• EPA Substance Registry System: Phenol, 3-methyl-, potassium salt(36294-16-3)

Safety Data

• Hazardous Substances Data: 36294-16-3(Hazardous Substances Data)

Upstream product

• 614-32-4 3-methylphenyl benzoate 

Downstream Products

• 1919-46-6 2,4,6-tris-m-tolyloxy-[1,3,5]triazine 
• 93871-78-4 2-amino-4,6-di(benzylamino)pyrimidine 
• 100763-49-3 N⁴-Benzyl-6-m-tolyloxy-pyrimidine-2,4-diamine 
• 344880-72-4 2-[(Furan-2-ylmethyl)-amino]-5-sulfamoyl-4-m-tolyloxy-benzenesulfonic acid phenyl ester 
• 85958-25-4 potassium salt of N-(2-furylmethyl)-5-sulfamoyl-4-(3-tolyloxy)orthanilic acid 
• 614-20-0 3-oxo-3-phenylpropionic acid 
• 614-32-4 3-methylphenyl benzoate 
• 1124-31-8 potassium 4-nitrophenolate 
• 2005-08-5 4-chlorophenyl benzoate 
• 93-99-2 benzoic acid phenyl ester 
• 1121-74-0 potassium 4-chlorophenoxide 
• 3118-78-3 potassium-3-nitrophenolate 
• 3586-14-9 3-phenoxytoluene 
• 14314-69-3 potassium 2,4-dinitrophenolate 

Relevant articles and documents

Kinetics and mechanism of nucleophilic displacement reactions of Y-substituted phenyl benzoates with cyanide Ion

Second-order rate constants (kCN-) have been measured for nucleophilic substitution reactions of Y-substituted phenyl benzoates (1a-r) with CN- ion in 80 mol % H2O/20 mol % DMSO at 25.0 ± 0.1 °C. The Bronsted-type plot is linear with βlg = -0.49, a typical βlg value for reactions reported to proceed through a concerted mechanism. Hammett plots correlated with σo and σ-constants exhibit many scattered points. In contrast, the Yukawa-Tsuno plot for the same reaction exhibits excellent linearity with pY = 1.37 and r = 0.34, indicating that a negative charge develops partially on the oxygen atom of the leaving aryloxide in the rate-determining step (RDS). Although two different mechanisms are plausible (i.e., a concerted mechanism and a stepwise pathway in which expulsion of the leaving group occurs at the RDS), the reaction has been concluded to proceed through a concerted mechanism on the basis of the magnitude of βlg and pY values.