363609-99-8

Basic information

• Product Name: bis(N,N'-diphenylbenzamidinato)norbornadieneruthenium(II)
• CAS NO: 363609-99-8
• Molecular Weight: 735.894
• Mol File: 363609-99-8.mol

Chemical Properties

• CAS DataBase Reference: bis(N,N'-diphenylbenzamidinato)norbornadieneruthenium(II)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(N,N'-diphenylbenzamidinato)norbornadieneruthenium(II)(363609-99-8)
• EPA Substance Registry System: bis(N,N'-diphenylbenzamidinato)norbornadieneruthenium(II)(363609-99-8)

Safety Data

• Hazardous Substances Data: 363609-99-8(Hazardous Substances Data)

Upstream product

• 2556-46-9 N,N'-diphenylbenzamidine 

Relevant articles and documents

Amidinato and triazenido complexes of ruthenium(II): X-ray crystal structure of the N,N′-diphenylformamidine fragmentation product [RuCl(NH2Ph) {PhNC(H)NPh} (Me2SO)2]

N,N′-Diphenylamidines, PhNC(R)NHPh (R = H, Me, Et, Ph), and 1,3-diaryltriazenes, ArNNNHAr (Ar = p -C6H4X, X = H, Cl, Me, OMe) react with ruthenium(II) complexes, [RuCl2(C7H8)]n, [RuCl2(CO)2]n and [RuCl2(Me2SO)4] in the presence of a base (NEt3 or Na2CO3) to afford a selection of bis(chelate) products [Ru{PhNC(R)NPh}2L2] and [Ru(ArNNNAr)2L2] (L = CO, Me2SO; L2 = C7H8). In contrast one particular combination - [RuCl2(Me2SO)4]/PhNC(H)NHPh/NEt3 - in refluxing dimethylformamide yields a novel amidine fragmentation product [RuCl(NH2Ph){PhNC(H)NPh}(Me2SO)2] which has been characterised by X-ray diffraction methods.