363624-99-1

Upstream product

• 7766-50-9 1-undecen-11-ylbromide 
• 873-55-2 sodium benzenesulfonate 

Downstream Products

• 853569-42-3 3-benzenesulfonyl-1,1,1-trifluoro-tridec-12-en-2-one 
• 363625-02-9 2-(9-benzenesulfonyl-nonyl)-oxirane 
• 363625-01-8 (R)-11-Benzenesulfonyl-undecane-1,2-diol 

Relevant academic research and scientific papers

A General Approach to Intermolecular Olefin Hydroacylation through Light-Induced HAT Initiation: An Efficient Synthesis of Long-Chain Aliphatic Ketones and Functionalized Fatty Acids

Herein, an operationally simple, environmentally benign and effective method for intermolecular radical hydroacylation of unactivated substrates by employing photo-induced hydrogen atom transfer (HAT) initiation is described. The use of commercially available and inexpensive photoinitiators (Ph2CO and NHPI) makes the process attractive. The olefin hydroacylation protocol applies to a wide array of substrates bearing numerous functional groups and many complex structural units. The reaction proves to be scalable (up to 5 g). Different functionalized fatty acids, petrochemicals and naturally occurring alkanes can be synthesized with this protocol. A radical chain mechanism is implicated in the process.

A new, practical and efficient sulfone-mediated synthesis of trifluoromethyl ketones from alkyl and alkenyl bromides

We report herein a new and efficient method to prepare trifluoromethyl ketones from the corresponding bromides through sulfones in good yields.