36385-68-9

Upstream product

• 15842-03-2 trans-IrCl(CO){PC₆H₅(C₂H₅)2} 
• 35972-25-9 [RhCl₃(CO)(P(C₂H₅)2C₆H₅)2] 

Downstream Products

• 77018-07-6 [IrCl₃(CO)(P(C₂H₅)2C₆H₅)(P(CH₃)2C₆H₅)] 
• 77018-06-5 trans-[IrCl(CO)(PEt₂Ph)(PMe₂Ph)] 
• 15842-03-2 trans-IrCl(CO){PC₆H₅(C₂H₅)2} 
• 77059-30-4 [IrCl₃(CO)(P(CH₃)2C₆H₅)2] 

Relevant academic research and scientific papers

Direct Oxidative Addition-Reductive Elimination Reactions Between trans- and or trans- (M = Rh or Ir, L = tertiary phosphine)

Complexes of the type trans- and .M = Rh or Ir, L = PMe2Ph or PEt2Ph, have been shown to react with each other, presumably by a double chloro-bridged intermediate, and undergo rapid oxidative addition-reductive elimination; phosphine exchange is much slower.Similar results were obtained when trans- was treated with trans-, M = Rh or Ir, for which rapid and complete conversion into trans- and occured. (31)P NMR data are given.