364751-01-9

Basic information

• Product Name: [Au(III)Cl₃(2-phenylthiazole)]
• CAS NO: 364751-01-9
• Molecular Weight: 464.553
• Mol File: 364751-01-9.mol

Chemical Properties

• CAS DataBase Reference: [Au(III)Cl₃(2-phenylthiazole)](CAS DataBase Reference)
• NIST Chemistry Reference: [Au(III)Cl₃(2-phenylthiazole)](364751-01-9)
• EPA Substance Registry System: [Au(III)Cl₃(2-phenylthiazole)](364751-01-9)

Safety Data

• Hazardous Substances Data: 364751-01-9(Hazardous Substances Data)

Upstream product

• 1826-11-5 2-phenylthiazole 
• 364751-00-8 [H(2-phenylthiazole)][Au(III)Cl₄] 
• 29156-65-8 sodium tetrachloroaurate(III) dihydrate 
• 10294-30-1 AuCl₃*4H₂O 

Downstream Products

• 364751-04-2 [Au(III)Cl₂(2-(2-thiazolyl)phenyl)(PPh₃)] 
• 364751-06-4 [Au(III)Cl(2-(2-thiazolyl)phenyl)(PPh₃)2]BF₄ 

Relevant articles and documents

Synthesis and reactivity of the five-membered cycloaurated complexes of 2-phenylthiazole

2-Phenylthiazole (Hphtz) reacted with H[AuCl4]·4H2O to give the salt [H(Hphtz)][AuCl4] (1), while the reaction of Hphtz with Na[AuCl4]·2H2O or AuCl3·4H2O afforded the adduct [AuCl3(Hphtz-N)] (2). When the adduct 2 was heated in 1,2-dichloroethane in the presence of AgBF4, cycloauration took place to produce [AuCl2(phtz-C1, N)] [phtz = 2-(2-thiazolyl)phenyl] (3). The reactivity of 3 towards Tl(acac) and PPh3 was investigated.