3650-60-0

Upstream product

• 16697-51-1 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-α-D-erythro-hex-2-enopyranoside 
• 140-29-4 phenylacetonitrile 
• 88714-25-4 (S)-((4aR,6S,7S,8R,8aS)-6-Methoxy-8-nitro-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-phenyl-acetonitrile 
• 25541-58-6 methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-erythro-hex-2-enopyranoside 
• 88714-29-8 (R)-((4aR,6S,7S,8R,8aS)-6-Methoxy-8-nitro-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-phenyl-acetonitrile 
• 16697-50-0 Methyl-2-O-acetyl-4,6-O-benzyliden-3-deoxy-3-nitro-α-D-glucopyranosid 

Relevant academic research and scientific papers

DENITRATION OF CARBOHYDRATE α-NITROEPOXIDES BY NUCLEOPHILES

Several nucleophiles were separately treated with methyl and phenyl 2,3-anhydro-4,6-O-benzylidene-3-deoxy-3-nitro-β-D-allopyranoside, to give 2-substituted aldos-3-ulose derivatives.In the latter case, the subsequent β-elimination of the aglyconic phenyl

REACTIONS OF METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-NITRO α- AND-β-D-ERYTHRO-HEX-2-ENOPYRANOSIDES WITH PHENYLACETONITRILE: PREPARATION AND STRUCTURAL DETERMINATION OF ADDUCTS AND AN ISOXAZOLE DERIVATIVE

Treatment of methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-α-D-erythro-hex-2-enopyranoside with phenylacetonitrile afforded adducts having the D-manno (2 and 3) and D-gluco configurations (4 and 5), the isoxazole 6, the cyano alkene 7, and the nitro alcoho