365404-30-4

Upstream product

• 365404-48-4 5-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-pentanoic acid ethyl ester 
• 113335-04-9 (R)-5-Benzyloxy-3-hydroxy-pentanoic acid ethyl ester 
• 64714-79-0 5-benzyloxy-3-oxo-pentanoic acid ethyl ester 
• 236427-78-4 (S)-((1-(benzyloxy)hex-5-en-3-yl)oxy)(tert-butyl)dimethylsilane 
• 91285-62-0 (S)-1-(benzyloxy)-3-hydroxyhex-5-ene 
• 365404-49-5 (S)-5-(benzyloxy)-3-(tert-butyldimethylsilyloxy)pentan-1-ol 
• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 

Downstream Products

• 900519-17-7 2,2-Dimethyl-propionic acid (E)-(S)-9-benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-4-methyl-non-3-enyl ester 
• 365404-37-1 (S)-1-[(2R,3S,6S)-6-(2-Benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-3-[(2S,6R)-4-methylene-6-(2-triisopropylsilanyloxy-ethyl)-tetrahydro-pyran-2-yl]-propan-2-ol 
• 365404-32-6 [(2R,3S,6S)-6-(2-Benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-acetaldehyde 
• 365404-31-5 (3S,6S)-6-(2-Benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-one 
• 365404-52-0 Acetic acid (3S,6S)-6-(2-benzyloxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl ester 
• 365404-53-1 (2R,3S,6S)-2-Allyl-6-(2-benzyloxy-ethyl)-3-methyl-tetrahydro-pyran 
• 900519-21-3 ((E)-(S)-1-(2-Benzyloxy-ethyl)-7-{2-[3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-propyl]-[1,3]dithian-2-yl}-4-methyl-hept-4-enyloxy)-tert-butyl-dimethyl-silane 
• 900519-23-5 (E)-(S)-13-Benzyloxy-11-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-8-methyl-tridec-7-en-4-ol 
• 900519-22-4 (E)-(S)-13-Benzyloxy-11-(tert-butyl-dimethyl-silanyloxy)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-8-methyl-tridec-7-en-4-one 
• 900519-18-8 [(E)-(S)-1-(2-Benzyloxy-ethyl)-7-iodo-4-methyl-hept-4-enyloxy]-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Unified total synthesis of pteriatoxins and their diastereomers

A unified total synthesis is reported to access all of the possible diastereomers of pteriatoxins A-C, with the use of an intramolecular Diels-Alder reaction as the key step to form the carbo-macrocyclic core structure. The C34/C35-diol protecting groups were found to have significant effects on both the exo/endo-selectivity and the exo-facial selectivity of the intramolecular Diels-Alder process. Copyright