365413-70-3

Downstream Products

• 1008797-13-4 methyl 4-[(phenylmethoxy)amino]hexanoate 
• 1008797-14-5 methyl 5-methyl-4-[(phenylmethoxy)amino]hexanoate 
• 1008797-16-7 methyl 5-methyl-4-[(phenylmethoxy)amino]heptanoate 
• 1008797-17-8 methyl 6-methyl-4-[(phenylmethoxy)amino]heptanoate 
• 1008797-20-3 methyl 4-[(phenylmethoxy)amino]tricyclo[3.3.1.1^3,7]decane-1-butanoate 
• 1008797-15-6 methyl 5,5-dimethyl-4-[(phenylmethoxy)amino]hexanoate 

Relevant academic research and scientific papers

Tin-free radical acylation reactions with methanesulfonyl oxime ether

A simple strategy involving thermal decomposition of the methanesulfonyl radical into the methyl radical and the subsequent transfer of an iodine atom or phenyl telluride group was used to develop a tin-free radical acylation reaction (see scheme; V-40 = 1,1′-azobis(cyclohexane-1-carbonitrile). The key was finding reaction conditions under which the I or PhTe transfer is faster than the direct addition of the alkyl radical to the methanesulfonyl ether.