36552-53-1Relevant academic research and scientific papers
A simple route to morpholine derivatives via copper-acetylide addition to carbodiimide in the presence of oxiranes
Samzadeh-Kermani, Alireza
, p. 248 - 256 (2020)
A novel catalytic multicomponent reaction for the synthesis of morpholine derivatives has been reported. The reactions involve terminal alkynes, carbodiimides, and oxiranes using [Cu (CH3CN)4]PF6, tBuOLi, and TB
Tuning the electronic structure of Mo-Mo quadruple bonds by N for O for S substitution
Hicks, Jamie,Ring, Sam P.,Patmore, Nathan J.
experimental part, p. 6641 - 6650 (2012/07/14)
A series of quadruply bonded dimolybdenum compounds of form Mo 2(EE′CCCPh)4 (EE′ = {NPh}2, Mo 2NN; {NPh}O, Mo2NO;{NPh}S, Mo2NS; OO, Mo 2OO) have been synthesised by ligand exchange reactions of Mo 2(O2CCH3)4 with the acid or alkali metal salt of {PhCCCEE′}-. The compounds Mo2NO, Mo2NS and Mo2OO were structurally characterised by single crystal X-ray crystallography. The structures show that Mo2NO adopts a cis-2,2 arrangement of the ligands about the Mo24+ core, whereas Mo2NS adopts the trans-2,2 arrangement. The influence of heteroatom substitution on the electronic structure of the compounds was investigated using cyclic voltammetry and UV-Vis spectroscopy. Simple N for O for S substitution in the bridging ligands significantly alters the electronic structure, lowering the energy of the Mo2-δ HOMO and reducing the Mo24+/5+ oxidation potential by up to 0.9 V. A different trend is found in the optoelectronic properties, with the energy of the Mo2-δ-to-ligand-π* transition following the order Mo2OO > Mo2NO > Mo2NN > Mo 2NS. Electronic structure calculations employing density functional theory were used to rationalise these observations.
