36625-33-9

Basic information

• Product Name: 2-Cyclohexen-1-one, 3-azido-
• CAS NO: 36625-33-9
• Molecular Formula: C6H7N3O
• Molecular Weight: 137.141
• Mol File: 36625-33-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 3-azido-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 3-azido-(36625-33-9)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 3-azido-(36625-33-9)

Safety Data

• Hazardous Substances Data: 36625-33-9(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 

Downstream Products

• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 129046-97-5 2-(4-bromophenyl)-1,5,6,7-tetrahydro-4H-indol-4-one 
• 129046-96-4 2-(4-chlorophenyl)-1,5,6,7-tetrahydro-4H-indol-4-one 
• 6206-30-0 2,3-diphenyl-1,5,6,7-tetrahydro-4H-indol-4-one 
• 14006-77-0 2-phenyl-1,5,6,7-tetrahydro-4H-indol-4-one 
• 35308-68-0 1,5,6,7-tetrahydro-2-methyl-4H-indol-4-one 
• 14006-78-1 2-(4-methylphenyl)-1,5,6,7-tetrahydro-4H-indol-4-one 
• 52035-11-7 N-<(3-oxo-2-cyclohexenyl)imino>triphenylphosphorane 

Relevant articles and documents

Vinyliminophosphorane-mediated preparation of 2-arylquinoline and 4-aryl-1-azaanthraquinone derivatives. X-Ray crystal structure of 1,2-dihydro-3H-indazolo[2,3-a]quinolin-4-one

The reaction of the iminophosphorane derived from 3-azidocyclohexan-2-enone with substituted cinnamyl aldehydes affords 2-aryl-tetrahydroquinoline derivatives, which are easily converted into 2-arylquinolones. By contrast, iminophosphorane derived from 2-azidocyclohex-2-enone reacts only with α,β-unsaturated aldehydes without substituent at β-position to give 5,6-dihydro-8(7H)quinolinones. The iminophosphorane derived from 2-azido-1,4-naphthoquinone reacts with substituted cinnamyl aldehydes providing directly 4-aryl-1-azaanthraquinones. The crystal and molecular structure of 1,2-dihydro-3H-indazolo[2,3-a]quinolin-4-ono has been solved by X-Ray analysis.