36637-44-2

Basic information

• Product Name: 4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAGNESIUM BROMIDE
• Synonyms: 4-(2-Tetrahydro-2H-pyranoxy)phenylMagnesiuM broMide solution 0.5 M in THF;4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide 0.5 M in Tetrahydrofuran;4-(2-Tetrahydropyranyloxy)phenylmagnesium bromide;4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAGNESIUM BROMIDE;4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAG NESIUM BROMIDE,0.5M SOLN IN THF;4-(2-tetrahydro-2h-pyranoxy)phenylmagnesium bromide solution;4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide, 0.5M solution in THF, AcroSeal;4-(2-Tetrahydropyranyloxy)phenylMagnesiuM broMide, 0.5M in 2-MeTHF
• CAS NO: 36637-44-2
• Molecular Formula: C₁₁H₁₃BrMgO₂
• Molecular Weight: 281.43
• Product Categories: Aryl;Grignard Reagents;Organometallic Reagents
• Mol File: 36637-44-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 65 °C
• Flash Point: 1 °F
• Appearance: Clear yellow to brown/Solution
• Density: 0.961 g/mL at 25 °C
• Storage Temp.: 2-8°C
• Sensitive: Air & Moisture Sensitive
• CAS DataBase Reference: 4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAGNESIUM BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAGNESIUM BROMIDE(36637-44-2)
• EPA Substance Registry System: 4-(2-TETRAHYDRO-2H-PYRANOXY)PHENYLMAGNESIUM BROMIDE(36637-44-2)

Safety Data

• Hazard Codes: F,C,F+,Xn
• Statements: 11-14-19-22-34-40-12-36/37
• Safety Statements: 16-23-26-36/37/39-45-36/37
• RIDADR: UN 2924 3/PG 2
• WGK Germany: 1
• HazardClass: 3
• Hazardous Substances Data: 36637-44-2(Hazardous Substances Data)

Usage

Uses

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium bromide can be used:In the preparation of C-2 and C-20-diaryl steroidal derivatives.As an intermediate in the synthesis of multiblock copolymers having fullerene backbone for possible applications in photovoltaic devices.

InChI:InChI=1/C11H13O2.BrH.Mg/c1-2-6-10(7-3-1)13-11-8-4-5-9-12-11;;/h2-3,6-7,11H,4-5,8-9H2;1H;/q;;+1/p-1/rC11H13BrMgO2/c12-13-9-4-6-10(7-5-9)15-11-3-1-2-8-14-11/h4-7,11H,1-3,8H2

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Relevant articles and documents

Triphenylbut-1-ene derivatives and pharmaceutical compositions and uses thereof

The disclosure relates to the compound 1-(p-β-dimethylaminoethoxyphenyl)-cis-1-(p-hydroxyphenyl)-2-phenylbut-1-ene, to pharmaceutical compositions containing it and to the use of the compound to produce an anti-oestrogenic effect in warm-blooded animals.