36639-10-8Relevant academic research and scientific papers
The stepped reaction of decafluorobiphenyl with thiophenol studied by in situ 19F NMR spectroscopy
Langner, Christian,Meier-Haack, Jochen,Voit, Brigitte,Komber, Hartmut
, p. 314 - 321 (2014/01/06)
Kinetic studies on the reaction of decafluorobiphenyl and di- and tetra(phenylthio)-substituted perfluorobiphenyl with thiophenol in the presence of triethylamine were performed by in situ 19F NMR spectroscopy to determine rate constants. In we
A STUDY OF THE SUBSTITUTION OF SOME FLUOROAROMATICS USING - (E = S or Se) AS A SOURCE OF THE EPh- NUCLEOPHILE
Blanchard, S. H.,Dean, P. A. W.,Manivannan, V.,Srivastava, R. S.,Vittal, J. J.
, p. 93 - 101 (2007/10/02)
A 207Pb NMR study of Pb(SPh)2/DMF mixtures, which are known to act as a source of the SPh- nucleophile, suggests that they contain species with the PbIIS3 kernel.To discover whether the carrier of SPh- could be -, the room-temperature reactions of (AsPh4) (1) with the representative substrates (C6F5)2, 2,4-C6H3(NO2)2F and C6F6 in CHCl3 (or CDCl3/CHCl3) have been investigated.The known compounds 4,4'-(C6F4)2 and 2,4-C6H3(NO2)2(SPh) are formed readily from the first and second substrates, but the conversion of C6F6 to 4-C6F4(SPh)2 is very slow under the conditions used.En-route to 4,4'-(C6F4)2, the new compound 4-C6F5*C6F4(SPh) is formed.For (C6F5)2 and 2,4-C6H3(NO2)2F, analogous but slower reactions are observed using (AsPh4) (2), as a source of SePh-, but no reaction of C6F6 with 2 was observed.In general, reactions of 2 are complicated by its ease of oxidation to Ph2Se2.
THE THIOLATE ANION AS A NUCLEOPHILE. PART XIII. REACTIONS OF SOME TIN(II) AROMATIC THIOLATES
Hynes, Rosemary C.,Peach, Michael E.
, p. 129 - 134 (2007/10/02)
The reactions of tin(II) benzenethiolate and p-toluenethiolate with various fluoroaromatics in DMF have been studied.Replacement of some of the aromatic fluorines by the thiolate group was observed.The tin(II) aromatic thiolates are comparable in reactivity in these reactions with lead(II) benzenethiolate.All new compound have been characterized by elemental analysis, and NMR (H-1 and F-19) and mass spectroscopy.
