366452-50-8

Basic information

• Product Name: RuCl₂(PPh₃)2(4,4'-dinitro-2,2'-bipyridine)
• CAS NO: 366452-50-8
• Molecular Weight: 942.74
• Mol File: 366452-50-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: RuCl₂(PPh₃)2(4,4'-dinitro-2,2'-bipyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl₂(PPh₃)2(4,4'-dinitro-2,2'-bipyridine)(366452-50-8)
• EPA Substance Registry System: RuCl₂(PPh₃)2(4,4'-dinitro-2,2'-bipyridine)(366452-50-8)

Safety Data

• Hazardous Substances Data: 366452-50-8(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 18511-72-3 4,4'-dinitro-2,2'-bipyridine 

Relevant articles and documents

Electrochemical and spectroscopic studies on RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N-N) complexes (N = pyridine derivatives and N-N = phenanthroline or bipyridine derivatives). X-ray structure of RuCl2(PPh3)2(phen)

A series of RuCl2(PPh3)2(N)2 and RuCl2(PPh3)2(N-N) complexes were synthesized from RuCl2(PPh3)3, (N)2 = pyridine (py), 4-(N,N-dimethylamino)pyridine (4-dmNpy), 4-tert-butylpyridine (4-tBu-py), 4-methylpyridine (4-Mepy), 4-vinylpyridine (4-Vpy), 4-phenylpyridine (4-Phpy), isonicotinamide (4-CONH2py), 4-cyanopyridine (4-CNpy) N-N = 1,10-phenanthroline (phen), 2,2′-bipyridine (bipy), 2,2′-bipyridine-4,4′-dimethoxy (MeO-bipy), 2,2′-bipyridine-4,4′-dimethyl (Me-bipy), 2,2′-bipyridine-4,4′dithiomethyl (MeS-bipy), 2,2′-bipyridine-4,4′-dichloro (Cl-bipy) and 2,2′-bipyridine-4,4′-dinitro (NO2-bipy). The complexes were characterized by elemental analysis, cyclic voltammetry and UV-Vis, NMR and IR spectroscopies. The structure of the RuCl2(PPh3)2(phen) was established by single crystal X-ray crystallography.