366483-08-1Relevant articles and documents
(R)-(4-(Benzyloxycarbonylphenyl)-3-hydroxy-4,4-dimethyl-2-pyrrolidinone) acrylate derivative as a chiral dienophile for the synthesis of enantiopure 2-aminocyclohexane carboxylic acids
Calmes, Monique,Didierjean, Claude,Martinez, Jean,Songis, Olivier
, p. 2173 - 2178 (2007/10/03)
An asymmetric Diels-Alder reaction between the enantiopure (R)-benzyl-4-(3-acryloyloxy-4,4-dimethyl-2-oxopyrrolidin-1-yl)-benzoate (R)-2 and the N-Z-aminodiene 3 proceeded with total endo diastereoselectivity and was facially controlled in favour of the (
Diels-Alder approaches to ring-functionalized cyclic β-amino acids
Wipf,Wang
, p. 8747 - 8751 (2007/10/03)
Catalytic asymmetric Diels-Alder reactions with aminodiene 1 and desymmetrized fumarate 8 were used for efficient access to dihydroxylated cis- and trans-aminocyclohexane β-amino acids. (C) 2000 Elsevier Science Ltd.