366784-96-5Relevant academic research and scientific papers
Synthetic equivalents of alkynyl and propargyl radicals
Boutillier,Zard
, p. 1304 - 1305 (2007/10/03)
Radicals derived from β-ketoesters can, depending on the position of the unpaired electron, represent synthetic equivalents to the high energy and elusive alkynyl radicals or to the stabilised and relatively unreactive propargyl radicals by application of
Intramolecular hydrophosphination/cyclization of phosphinoalkenes and phosphinoalkynes catalyzed by organolanthanides: Scope, selectivity, and mechanism
Douglass,Stern,Marks
, p. 10221 - 10238 (2007/10/03)
Organolanthanide complexes of the general type Cp′2LnE(TMS)2 (Cp′ = η/5-Me5C5; Ln = La, Sm, Y, Lu; E = CH, N; TMS = SiMe3) serve as effective precatalysts for the rapid intramolecular hydro
